In the case of poly the ingredients (solids) are carried in either a oil base or a water base but (with out getting technical) poly ingredients react with each other and cure and bond. The latter action is what takes more time. In some cases the oil based actually contains more of the poly solids but newer water based (esp. floor grade) poly has plenty of solids.
I would seriously question "throwing" a oil base over water base in just a couple of hours. Personally I don t know why you would want to put oil over water based poly in the first place.
Oil based stains take longer for the oil to evaporate (it has soaked in) and that is why the delay before applying a top coat that could seal in the residual "oil" and possibly prevent the top coat from adhering..
- LesB
The answer as to why is speed and color.
In a remodeling or construction environment, (which I did for decades) speed is how you make money. Oil based stains have to dry longer. If you can put color and a first coat on, and get it to match an existing item, all in one day, it means you re ahead of the game.
As for color, oil based poly is yellower, and older projects usually used oil based poly (waterbased products are aa lot more common now than they used to be!). So, to get a new piece to match an old piece, oil based is sometimes required (and easier than trying to match with pigments or colorants, even toners).
There were many times when I stained something (flooring, shelving, etc) first thing in the morning, put the first coat of poly on before lunch, and a second, sometimes even a third on in the afternoon (on a long day). The next day, you can sand and put a final one or two coats on. Waterbased always dried faster… and was the first choice, if it worked color-wise, or wear-wise. But, like I said earlier, in today s reality, there are oil based polys that dry to a point where you can recoat in just a few hours.
I am still not convinced of the water over oil vs. oil over water…. Guess I will go do some research online later today.
Anyway, I m glad the OP has found success with more coats of the same product, instead of having to try mixing.
- Axis39