I don't think it would curl when heat was removed, but the glue would still be hot at that point and with nothing clamping it, I'd opt for clamps and good ole fashioned wood glue. How thick is the veneer you want to apply to the 1/64" plywood. I don't think that the lamination would be subject to curling due to the face that the plywood you want to use as a substrate is already a series of veneers. I'd just make sure your moisture contents were low and similar with both the veneer and the 1/64" plywood before gluing them together.